Chemistry, Vol 5, No 2 (2012)

Cracking of Heavy Oil at Presence of Zeolite Y Modified of Nickel Nanopowder

Тагир Муратович Мурзагалеев

Abstract


Process of thermal and catalytic cracking of heavy oil at presence of zeolite Y containing nickel nanopowder is studied at temperature 450 °С, pressure 0,5 … 0,7 МПа and durations of reaction 60 and 120 minutes It is shown, that the greatest yield of the distillate fractions boiling up to 350 °С is obtained via crude oil catalytic cracking by an addition of 5 % mas. catalyst 2,0 % Ni/HY during of experiment of 60 min, it is 67,1 %. Data of spectrometry of a nuclear magnetic resonance Н1, group and material constitution of products of thermal and catalytic cracking of heavy oil are cited. It is shown, that liquid product of catalytic cracking of heavy oil with the additive of 2,0 % Ni/HY contained the least quantity of resins and asphaltenes and grater quantity of oils in comparison with liquid products of thermal and catalytic cracking by addition catalyst HY.