The redox properties of new binuclear μ-vinylidene complexes Cp(CO)₂RePt(μ-C¹=C²HPh)LL′ [L = СO, L′ = PPh₃ (1); L = СO, L′ = P(OPr-i)₃ (2); L = L′ = PPh₃ (3); L = L′ = P(OPr-i)₃ (4)] were studied by electrochemical methods at a platinum, a glassed carbon and a dropping mercury electrodes in acetonitrile solutions. It was established that one-electron oxidation of 3 and 4 results in a cleavage of the Re-Pt and Pt-C¹ bonds affording vinylidene complex Cp(CO)₂Re=C=CHPh and [PtL₂] fragments. In contrast to complexes 3 and 4, one-electron oxidation of 1 and 2 is reversible, indicating the greater electrochemical stability of lasts relative to 3 and 4.