Syntheses and physical-chemical properties of phenylvinylidene complexes with MnPt core, containing diphenylphosphine ligand at the platinum atom
Oleg S Chudin, Victor V Verpekin, Alexander A Kondrasenko, Nina I Pavlenko, Anatoly I Rubaylo
Abstract
A synthetic approach to the new heterobinuclear µ-phenylvinylidene complexes Cp(CO)2MnPt(m-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)3 (2)], containing diphenylphosphine ligand at the platinum atom, was developed. The compounds were studied by IR and NMR spectroscopy. Their molecular structures were proposed based on IR, NMR spectroscopic data.