Chemistry, Vol 13, No 2 (2020)

Application of the CHNS-analysis for studying of polyoxometallates and ionic liquids in the catalytic systems

Olga S Koscheeva, Lidia I Kuznetsova, Nina I Kuznetsova

Abstract


The method of CHNS-analysis in combination with 31P NMR and UV-VIZ spectroscopy was used to study polyoxometallates and ionic liquids as components of liquid-phase catalytic systems. The composition of imidazolium and TBA salts of tungstоphosphate anions active in the olefin oxidation with H2O2 was determined. A method for quantification of [BMIm]Br, Bu4NBr, Bu4NHSO4 in solutions using the C, N, S analysis is proposed. The capabilities of the technique with applying IL to an inert porous support are evaluated. Using the obtained results, the effect of ionic liquids in combination with a Pt/C catalyst and H3PMo12O40 heteropolyacid in the oxidation of cyclohexane with О2-Н2 gas mixture was determined.