Electrocatalytic resorcinol oxidation by active oxygen forms in situ generated in conjugate reactions on Pt and Pb/PbO2 anodes and mesostructured carbon cathode СМК - 3
Галина Васильевна Корниенко, Татьяна Александровна Кенова, Василий Леонтьевич Корниенко, Алексей Александрович Кукушкин
Abstract
Kinetics and selectivity of indirect electrocatalytic resorcinol oxidation by active oxygen forms (AOF) in situ generated from oxygen in gas diffusion electrode (GDE) mesostructured carbon CMK-3 and Pt, Pb/PbO2 at different pH were studied. The high resorcinol oxidation process effectivity in both Pt-GDE at pH=10 (99%) and Pb/PbO2 + Fe2+ at рН=2 (99%) systems was shown; the resorcinol oxidation scheme was proposed.