Work is devoted by studying of a technique of preparation for competitive activity of volleyball players of 14-15 years taking into account properties of attention. Continuous interactions of players with a ball and among themselves promote improvement of deep and peripheral sight, accuracy and orientation in space. Besides, the volleyball develops also instant switching of attention from one object on another, increases muscular feeling and ability to fast alternations of tension and relaxations of muscles, and also ability to focus attention on the most important point in various game situations. Research helped to define, what properties of attention are most developed at players of various roles and who demand improvement. Having introduced the technique including 38 psycho-technical games-exercises we drew a conclusion, they can be used as a development tool of properties of attention as by the end of research in experimental group the gain of indicators of properties of attention was observed.